119 This substance, when in quantities of not more than 11.5 kg (25.3 pounds), with not less than 10 percent water, by mass, also may be classed as Division 4.1, provided a negative test result is obtained when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). The numbers and letters in the special provisions column are referred to in 49 CFR 172.102 with an explanation of their meanings. This entry applies to machinery or apparatus containing hazardous materials as a residue or as an integral element of the machinery or apparatus. Metal: 11A, 11B, 11N, 21A, 21B and 21N, b. The organic peroxide must be type D, E, or F, not requiring temperature control. When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. 350 Ammonium bromate, ammonium bromate aqueous solutions, and mixtures of a bromate with an ammonium salt are forbidden for transport. What is Column 7 of the hazardous materials Table? However this examination is required when the conditions of 180.605(f) are met. A100 Lithium ion cells and batteries must be offered for transport at a state of charge not exceeding 30 percent of their rated capacity. Navigate by entering citations or phrases The receptacles must be constructed with glass double walls having the space between the walls vacuum insulated and each receptacle must be transported in an outer packaging with sufficient cushioning and absorbent materials to protect the receptacle from damage. 172-29, 41 FR 15996, Apr. 35 Antimony sulphides and oxides which do not contain more than 0.5 percent of arsenic calculated on the total mass do not meet the definition of Division 6.1. 32 Polymeric beads and molding compounds may be made from polystyrene, poly(methyl methacrylate) or other polymeric material. Lading in unlined tanks must be inhibited so that the corrosive effect on steel is not greater than that of hydrofluoric acid of 65 percent concentration. W31 Non-bulk packagings must be hermetically sealed. B68 Sodium must be in a molten condition when loaded and allowed to solidify before shipment. switch to drafting.ecfr.gov. 65 The group of alkaline earth metals includes magnesium, calcium, strontium, and barium. The requirements of 173.24(g)(1) and 173.27(c) do not apply. Use the navigation links in the gray bar above to view the table of contents that this content belongs to. W8 Vessel stowage category for pyrophoric thorium metal or pyrophoric uranium metal is D as defined in 172.101(k)(4). N83 This material may not be transported in quantities of more than 11.5 kg (25.4 lbs) per package. A2 Single packagings are not permitted on aircraft. The material may only be loaded with Class 3, Class 8, and Division 4.1 materials in Packing Group II or III. 172.101 Hazardous Materials Table (HMT). B33 MC 300, MC 301, MC 302, MC 303, MC 305, MC 306, and DOT 406 cargo tanks equipped with a 1 psig normal vent used to transport gasoline must conform to Table I of this Special Provision. 31 Materials which have undergone sufficient heat treatment to render them non-hazardous are not subject to the requirements of this subchapter. IBCs must have a device to allow venting. 6 This material is poisonous-by-inhalation and must be described as an inhalation hazard under the provisions of this subchapter. 135 Internal combustion engines installed in a vehicle must be described using Vehicle, flammable gas powered or Vehicle, flammable liquid powered, as appropriate. When column 7 of the Hazardous Materials Table (49 CFR 172.101) includes a special provision code for an entry in the table, the requirement of that code - or codes, there may be several of them - is in addition to the general packaging requirements of 173.24 and any other applicable packaging requirements in Part 173. d. A chemical under pressure with components meeting the properties of: Class 1 (explosives); Class 3 (liquid desensitized explosives); Division 4.1 (self-reactive substances and solid desensitized explosives); Division 4.2 (substances liable to spontaneous combustion); Division 4.3 (substances which, in contact with water, emit flammable gases or toxic gases); Division 5.1 (oxidizing substances); Division 5.2 (organic peroxides); Division 6.2 (Infectious substances); or, Class 7 (Radioactive material), must not be offered for transportation under this description. 134 This entry applies only to vehicles powered by wet batteries, sodium batteries, lithium metal batteries or lithium ion batteries, and equipment powered by wet batteries or sodium batteries that are transported with these batteries installed. For criteria in determining what is a new lighter design, see 173.308(b)(1). Each inner packaging contains not more than 30 mL; b. If a tank car tank is equipped with a reclosing pressure relief valve, the tank must also be equipped with a vacuum relief valve. B85 Cargo tanks must be marked with the name of the lading in accordance with the requirements of 172.302(b). Table 3 authorizes Large Packagings for specific proper shipping names through the use of IB Codes assigned in the 172.101 table of this subchapter. 21 This material must be stabilized by appropriate means (e.g., addition of chemical inhibitor, purging to remove oxygen) to prevent dangerous polymerization (see 173.21(f) of this subchapter). 49 CFR -172.101 Hazardous Materials Table info - MaselliWeb (h) Column 7: Special provisions. Each in such a manner as to prevent short circuits, accidental operation, and significant movement relative to the cargo transport unit under the shocks, loadings, and vibrations normally incident to transport. e. When transported by highway, rail, vessel, or as cargo on an aircraft, neutron radiation detectors containing not more than 1 gram of boron trifluoride, including those with solder glass joints are not subject to any other requirements of this subchapter provided they meet the requirements in paragraph a of this special provision and are packed in accordance with paragraph b of this special provision. Components classed as Division 6.1, Packing Group I, or Class 8, Packing Group I, must not be offered for transportation and transported under this description. When such batteries are transported in accordance with 173.185(c), the total lithium content of all lithium metal cells contained in the battery must not exceed 1.5 g and the total capacity of all lithium ion cells contained in the battery must not exceed 10 Wh. This entry does not apply to life saving appliances described in 173.219 (UN2990 and UN3072). 357 A bulk packaging that emits hydrogen sulfide in sufficient concentration that vapors evolved from the crude oil can present an inhalation hazard must be marked as specified in 172.327 of this part. In addition to the packaging required in 173.4a, each glass inner packaging must be placed in a sealed plastic bag compatible with ethylene oxide and capable of containing the contents in the event of breakage or leakage of the glass inner packaging; and. A37 This entry applies only to a material meeting the definition in 171.8 of this subchapter for self-defense spray. (6) A code containing the letter R refers to a special provision which applies only to transportation by rail. How to Read the Hazardous Materials Table Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. (i) Column 8: Packaging authorizations. c. Every installed inflation cylinder, as associated equipment of the life-saving appliance, must be packed within the protective packaging of the life raft and the life raft itself must otherwise be in compliance with 173.219. d. The serial number for each cylinder must be recorded as part of the life-saving appliance service record by the U.S. Coast Guard-approved servicing facility. The batteries must be securely attached to the interior structure of the cargo transport unit (e.g., by means of placement in racks, cabinets, etc.) information or personal data. 352 Ammonium chlorite, ammonium chlorite aqueous solutions, and mixtures of a chlorite with an ammonium salt are forbidden for transport. Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. N7 The hazard class or division number of the material must be marked on the package in accordance with 172.302 of this subchapter. in Column (7) of the 172.101 Hazardous Materials Table for a specific haz-ardous material; and marine portable tanks conforming to 46 CFR part 64 are authorized. Column 7 specifies codes for special provisions applicable to hazardous materials. The packaging may not be loaded with a material outside of the packaging's design temperature range. 54 Maneb or maneb preparations not meeting the definition of Division 4.3 or any other hazard class are not subject to the requirements of this subchapter when transported by motor vehicle, rail car, or aircraft. individual packaging placed or stacked and secured by strapping, shrink or stretch-wrapping or other suitable means to a pallet). learn more about the process here. be marked with the hydrostatic pressure test marking specified in 173.24a(b)(4). Non-specification bulk bins are authorized. b. A10 When aluminum or aluminum alloy construction materials are used, they must be resistant to corrosion. N40 This material is not authorized in the following packagings: a. N25 Steel single packagings are not authorized. will also bring you to search results. Retain a copy of each notification of pilot-in-command if requested for up to 30 days Which one of the following hazardous materials is NOT excepted from the quantity limitations in 175.75? Hazardous materials not necessary for the safe and proper operation of the cargo transport unit must not be transported within the cargo transport unit. Alcoholic beverages containing more than 24 percent but not more than 70 percent alcohol by volume must be transported as materials in Packing Group III. Prohibited means bottom openings are prohibited, and Prohibited for liquids means bottom openings are authorized for solid material only. W9 When offered for transportation by water, the following Specification packagings are not authorized unless approved by the Associate Administrator: woven plastic bags, plastic film bags, textile bags, paper bags, IBCs and bulk packagings. The Code of Federal Regulations (CFR) is the official legal print publication containing the codification of the general and permanent rules published in the Federal Register by the departments and agencies of the Federal Government. We recommend you directly contact the agency responsible for the content in question. A189 Except where the defining criteria of another class or division are met, concentrations of formaldehyde solution: a. When phlegmatized with water and inorganic inert material, the content of urea nitrate must not exceed 75 percent by mass and the mixture should not be capable of being detonated by test 1(a)(i) or test 1(a)(ii) in the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). For transportation by aircraft, articles, machinery, or apparatus, may not contain any material forbidden for transportation by passenger or cargo aircraft. 45 Temperature should be maintained between 18 C (64.4 F) and 40 C (104 F). 372 This entry applies to asymmetric capacitors with an energy storage capacity greater than 0.3 Wh. Based on the volatility class determined by using ASTM D 439 and the Reid vapor pressure (RVP) of the particular gasoline, the maximum lading pressure and maximum ambient temperature permitted during the loading of gasoline may not exceed that listed in Table I. TP17 Only inorganic non-combustible materials may be used for thermal insulation of the tank. For UN2031 with more than 55% nitric acid, rigid plastic IBCs and composite IBCs with a rigid plastic inner receptacle are authorized for two years from the date of IBC manufacture. 55 This device must be approved in accordance with 173.56 of this subchapter by the Associate Administrator. N11 This material is excepted for the specification packaging requirements of this subchapter if the material is packaged in strong, tight non-bulk packaging meeting the requirements of subparts A and B of part 173 of this subchapter. Prior to repacking into the life-saving appliance, an installed inflation cylinder must successfully meet and pass all inspection and test criteria and standards of the raft manufacturer and the vessel Flag State requirements for cylinders installed as part of life-saving appliances, self-inflating (UN2990) used on marine vessels. When a special provision specifies packaging or packaging requirements - 108 Fireworks must be so constructed and packaged that loose pyrotechnic composition will not be present in packages during transportation. (2) They must be packed in strong outer packagings and the completed package must be capable of withstanding a 1.8 meter (5.9 feet) drop without leakage of gas contents from detectors. TABLE 2 lists . Insulating materials may not promote corrosion to steel when wet. 59 Ferrocerium, stabilized against corrosion, with a minimum iron content of 10 percent is not subject to the requirements of this subchapter. iv. (6) The rate of oxygen release from the outer packaging does not exceed 15 mL per hour. Portable tank special provisions are designated with the abbreviation TP (tank provision) and are assigned to specific hazardous materials in Column (7) of the 172.101 Table. N12 Plastic packagings are not authorized. **Self-reactive materials that are thermally unstable and that N86 UN pressure receptacles made of aluminum alloy are not authorized. A copy of the approval must accompany each shipment. Single unit tank car tanks must have a reclosing pressure relief device having a start-to-discharge pressure set at no more than 1551 kPa (225 psig). b. full text search results b. The tank must have been designed and constructed to be capable of withstanding full vacuum. 340 This entry applies only to the vessel transportation of nickel-metal hydride batteries as cargo. TP45 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. UN2258, 1,2-Propylenediamine: In HM-260B, PHMSA removed special provision A6 from column (7) of the . 169 This entry applies to lighter refills (see 171.8 of this subchapter) that contain a Division 2.1 (flammable) gas but do not contain an ignition device. B5 Only ammonium nitrate solutions with 35 percent or less water that will remain completely in solution under all conditions of transport at a maximum lading temperature of 116 C (240 F) are authorized for transport in the following bulk packagings: MC 307, MC 312, DOT 407 and DOT 412 cargo tanks with at least 172 kPa (25 psig) design pressure. 8 A hazardous substance that is not a hazardous waste may be shipped under the shipping description Other regulated substances, liquid or solid, n.o.s., as appropriate. Primary receptacles must conform to the general packaging requirements of subpart B of part 173 of this subchapter and may not leak. Lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit must use the proper shipping name Lithium batteries installed in cargo transport unit found in the 172.101 Hazardous Materials Table. The material is packaged in a DOT Specification 4BW240 cylinder, or in a DOT-51 portable tank. As a A9 For combination packagings, if plastic bags are used, they must be packed in tightly closed metal receptacles before packing in outer packagings. B55 Water-tight, sift-proof, closed-top, metal-covered hopper cars, equipped with a venting arrangement (including flame arrestors) approved by the Associate Administrator are also authorized. b. Used or spent dry batteries of both non-rechargeable and rechargeable designs, with a marked rating up to 9-volt that are combined in the same package and transported by highway or rail for recycling, reconditioning, or disposal are not subject to this special provision or any other requirement of the HMR. 196 The nitrocellulose must meet the criteria of the Bergmann-Junk test or methyl violet paper test in the UN Manual of Tests and Criteria, Appendix 10 (IBR, see 171.7 of this subchapter). TP12 This material is considered highly corrosive to steel. If a frangible disc is required in series with the reclosing pressure relief device for the specified portable tank, the alternative portable tank must be fitted with a frangible disc in series with the reclosing pressure relief device; and, (1) When two effective means are specified, the alternative portable tank is fitted with bottom openings having two or three effective means of closure or no bottom openings; or, (2) When three effective means are specified, the portable tank has no bottom openings or three effective means of closure; or. ; and. Examples of such vehicles are cars, motorcycles, trucks, locomotives, scooters, three- and four-wheeled vehicles or motorcycles, lawn tractors, self-propelled farming and construction equipment, boats, and aircraft. Special Provision Letter Codes Used in Hazmat Table, Column 7 Column 7 uses eight letter codes. 23 This material may be transported under the provisions of Division 4.1 only if it is so packed that the percentage of diluent will not fall below that stated in the shipping description at any time during transport. c. Self-propelled vehicles or equipment that also contain an internal combustion engine must be described using the entries Engine, internal combustion, flammable gas powered or Engine, internal combustion, flammable liquid powered or Vehicle, flammable gas powered or Vehicle, flammable liquid powered, as appropriate. However, button cell batteries installed in equipment (including circuit boards) need not be considered; and, c. The shipping paper must indicate UN 3091 Lithium metal batteries packed with equipment or UN 3481 Lithium ion batteries packed with equipment, as appropriate. An important, but often overlooked, requirement for the safe and regulatory compliant transportation of a HazMat is an understanding of the special provisions in column 7 of the Hazardous Materials Table. In addition, MC 312 and DOT 412 cargo tank motor vehicles must: a. The standards for CTMVs capable of transporting multiple hazardous materials for blasting in bulk and non-bulk packagings (i.e., a multipurpose bulk truck (MBT)). These articles must be tested in accordance with Test series 6(c) of Part I of the UN Manual of Tests and Criteria (incorporated by reference; see 171.7 of this subchapter), with no explosion of the device, no fragmentation of device casing or pressure vessel, and no projection hazard or thermal effect that would significantly hinder fire-fighting or other emergency response efforts in the immediate vicinity. The toy plastic or paper caps must be in the form of sheets, strips, rolls, or individual caps; b.
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